12653-62-2Relevant academic research and scientific papers
Vaporization of Sr- and Mg-Doped Lanthanum Gallate and Implications for Solid Oxide Fuel Cells
Kuncewicz-Kupczyk, Wioletta,Kobertz, Dietmar,Miller, Miroslaw,Singheiser, Lorenz,Hilpert, Klaus
, p. E276-E281 (2001)
Vaporization of the La0.85Sr0.15Ga0.85Mg0.15O 2.85, and La0.90Sr0.10Ga0.80Mg0.20O 2.85 perovskite phases was investigated by the use of Knudsen e
Electron spin resonance matrix isolation studies of 27Al16,17O, 69,71Ga16,17O and 115In16,17O: Observed hyperfine interactions compared with ab initio theoretical results
Knight Jr., Lon B.,Kirk, Thomas J.,Herlong, John,Kaup, John G.,Davidson
, p. 7011 - 7019 (2007/10/03)
Electron spin resonance (ESR) studies are reported for Al16,17O, Ga16,17O, and In16,17O isolated in neon matrices at 4 K. Except for Al16O, no previous ESR measurements have been reported for these X 2Σ diatomic radicals. The pulsed laser vaporization of the metals in the presence of 16O2 and 17O2 produced high quality ESR spectra of these metal oxide radicals whose nuclear hyperfine interactions (A tensors) were fully resolved for both the metal and oxygen nuclei. An analysis of the experimental spin densities in combination with different types of theoretical calculations provided detailed information concerning the electronic structure trends going down this metal oxide group. Increased p-orbital spin density on oxygen was observed for the heavier metal oxide radicals. Nonrelativistic ab initio calculations with an extended basis set and the UB3LYP method reproduced the trends in the isotropic and dipolar hyperfine interactions. All-electron CI calculations, restricted open-shell Hartree-Fock (ROHF) wave functions, and unrestricted Hartree-Fock wave functions gave results very different from experiment and from each other for the isotropic interaction. All calculations were in fair agreement with each other for the dipolar interaction and provided an assignment of the sign for that term.
Reactions of Gallium Atoms
Mitchell, S. A.,Hackett, P. A.,Rayner, D. M.,Cantin, M.
, p. 6148 - 6154 (2007/10/02)
Ground-state Ga(4p12P1/2) atoms are produced by visible multiphoton dissociation of trimethylgallium and monitored by resonance fluorescence excitation in a pulsed laser photolysis-laser fluorescence arrangement.Reactions
