126556-70-5Relevant academic research and scientific papers
Generation and Cycloadditions of 2-(N-acylamino)-1-thia-1,3-dienes part III: Control of diastereoselectivity using homochiral auxiliaries
Bell, Andrew S.,Fishwick, Colin W. G.,Reed, Jessica E.
, p. 3219 - 3234 (2007/10/03)
Activated 2-(N-acylamino)-1-thia-1,3-dienes undergo efficient diastereoselective Diels-Alder cycloadditions giving access to thiopyrans of high optical purity. By variation of the position and nature of the chiral auxiliaries we have been able to induce a
GENERATION AND CYCLOADDITIONS OF 2-(N-ACYLAMINO)-1-THIA-1,3-DIENES. PART II. RATIONALIZATION OF REACTIVITY USING AN FMO APPROACH.
Barnish, Ian T.,Fishwick, Colin W. G.,Hill, David R.,Szantay, Csaba
, p. 7879 - 7898 (2007/10/02)
2-(N-Acylamino)-1-thia-1,3-dienes undergo regiospecific and stereoselective Diels-Alder cycloaddition to electron deficient, non-activated, and electron rich alkenes to give usefully functionalised dihydrothiopyrans in good yields.
GENERATION AND CYCLOADDITIONS OF 2-(N-ACYLAMINO)-1-THIA-1,3-DIENES
Barnish, Ian T.,Fishwick, Colin W. G.,Hill, David R.,Szantay, Csaba, Jr.
, p. 4449 - 4452 (2007/10/02)
2-(N-Acylamino)-1-thia-1,3-dienes are a new class of reactive hetero-1,3-diene which can be generated in situ via acylation of α,β-unsaturatedthioamides.These systems undergo Diels-Alder cycloadditon with electron deficient, non-activated and electron ric
