126566-72-1

Upstream product

• 591-50-4 iodobenzene 
• 119072-54-7 2,6-dimethylphenyl isonitrile 
• 557-20-0 diethylzinc 
• 93-55-0 1-phenyl-propan-1-one 
• 87-62-7 2,6-dimethylaniline 
• 18109-39-2 N-(2,6-diimethylphenyl)benzamide 
• 74-96-4 ethyl bromide 
• 59387-01-8 N-(2,6-dimethylphenyl)benzenecarboximidoyl chloride 

Downstream Products

• 93-55-0 1-phenyl-propan-1-one 
• 106700-21-4 2-Chloro-N-(2,6-dimethyl-phenyl)-N-((E)-1-phenyl-propenyl)-acetamide 

Relevant academic research and scientific papers

Chiral phosphine-phosphoramidite ligands for highly efficient Ir-catalyzed asymmetric hydrogenation of sterically hindered N-arylimines

A mild and general iridium-catalyzed, highly enantioselective hydrogenation of sterically hindered N-arylimines with a new H8-BINOL-derived phosphine-phosphoramidite ligand has been developed. The present catalytic system features high turnover numbers (up to 100000) and good to perfect enantioselectivities (up to 99% ee) for the hydrogenation of a variety of sterically hindered N-arylimines.

Imidoylstannanes, Improved Preparation and Uses as Acylanion Equivalents

An improved preparation of imidoylstannanes, by reaction of triorganostannyllithiums with imidoyl chlorides, is reported.This reaction is effective when phenyl or methyl groups are substituents on the tin atom, and when N-aryl C-alkyl or C-aryl imidoyl chlorides are used.After reaction with acyl chlorides, imidoylstannanes led to high yields of α-keto imines, which can be further hydrolysed into α-diketones.Transmetallation with organolithiums selectively gave the corresponding lithium reagents which showed a normal behaviour with alkyl halides, silicon halides, epoxides or chloroformates, leading to functional imines, hydrolysable to the corresponding ketones.This route forms a new entry to Walborski reagents.

Synthesis and Herbicidal Activity of N-(1-Arylethenyl)-2-chloroacetamides

N-(1-Alkenyl)-2-chloroacetamides, which bear an aryl substituent at the 1-position of the alkenyl moiety, were synthesized and their herbicidal activities were tested.Some of them were active against paddy field weeds.In particular, a new type of chloroac

Transition Metal-catalyzed Coupling of zinc with Aromatic Iodide

zinc, prepared by α-addition of organozinc to aryl isocyanide, was coupled with aromatic iodide in the presence of palladium or nickel catalyst to give the corresponding N-aryl aromatic imine.