1265682-42-5

Basic information

• Product Name: 4-fluoro-1,2-bis(trimethylsilyl)benzene
• Synonyms: 4-fluoro-1,2-bis(trimethylsilyl)benzene
• CAS NO: 1265682-42-5
• Molecular Weight: 240.468
• Mol File: 1265682-42-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 4-fluoro-1,2-bis(trimethylsilyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 4-fluoro-1,2-bis(trimethylsilyl)benzene(1265682-42-5)
• EPA Substance Registry System: 4-fluoro-1,2-bis(trimethylsilyl)benzene(1265682-42-5)

Safety Data

• Hazardous Substances Data: 1265682-42-5(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 2369-37-1 1,2,-dibromo-4-fluorobenzene 
• 1435-49-0 3,4-dichlorofluorobenzene 

Relevant articles and documents

Copper-Free Double Silylation of 1,2-Dibromobenzenes Using a Mg/LiCl/DMI System

The reaction of 1,2-dibromobenzenes with chlorotrimethylsilane efficiently proceeded in the presence of Mg and LiCl in DMI under mild conditions, giving 1,2-bis(trimethylsilyl)benzenes in good to high yields. The reaction of 1,2-dibromobenzenes with chlorodimethylsilane under the same conditions afforded the corresponding 1,2-bis(dimethylsilyl)benzenes in high yields. Functional group transformations of 1,2-bis(trimethylsilyl)benzene were conducted to demonstrate the synthetic utility.

Synthesis of 1,2-bis(trimethylsilyl)benzene derivatives from 1,2-dichlorobenzenes using a hybrid metal Mg/CuCl in the presence of LiCl in 1,3-dimethyl-2-imidazolidinone

A practical and safe synthesis of 1,2-bis(trimethylsilyl)benzene from 1,2-dichlorobenzene and Me3SiCl was achieved by use of a hybrid metal of Mg and CuCl in the presence of LiCl in 1,3-dimethyl-2-imidazolidinone (DMI). This method does not req