126571-11-7Relevant academic research and scientific papers
Zinc-catalyzed silylation of terminal alkynes
Rahaim Jr., Ronald J.,Shaw, Jared T.
, p. 2912 - 2915 (2008)
(Chemical Equation Presented) A rapid and high-yielding silylation of terminal alkynes employing TMSOTf and catalytic quantities of Zn(OTf) 2 has been developed. The reaction works well for a variety of substrates including reactive esters. Fifteen examples with yields of >90% are reported.
