1265899-49-7Relevant academic research and scientific papers
Exploring a unique reactivity of N-heterocyclic carbenes (NHC) in rhodium(III)-catalyzed intermolecular C-H activation/annulation
Ghorai, Debasish,Choudhury, Joyanta
, p. 15159 - 15162 (2014)
Disclosed herein is the unique conjugative role of N-heterocyclic carbene (NHC) ligands as a directing group in aromatic C-H activation, coupled with a facile NHC-alkenyl annulative reductive elimination which guided the RhIII-catalyzed intermo
Green-blue emitters: NHC-based cyclometalated [Pt(C∧C)(acac)] complexes
Unger, Yvonne,Meyer, Dirk,Molt, Oliver,Schildknecht, Christian,Muenster, Ingo,Wagenblast, Gerhard,Strassner, Thomas
, p. 10214 - 10216 (2010)
White on target: Platinum(II) complexes with cyclometalated 1-phenylimidazole ligands (see picture: R=2,3-OC6H4) show photophysical properties in the blue region of the visible spectrum, thus giving them the potential to be used as the blue component of white-light-emitting diodes. Copyright
Highly active bidentate N-heterocyclic carbene/ruthenium complexes performing dehydrogenative coupling of alcohols and hydroxides in open air
Wang, Zhi-Qin,Tang, Xiao-Sheng,Yang, Zhao-Qi,Yu, Bao-Yi,Wang, Hua-Jing,Sang, Wei,Yuan, Ye,Chen, Cheng,Verpoort, Francis
, p. 8591 - 8594 (2019/07/25)
Eight bidentate NHC/Ru complexes, namely [Ru]-1-[Ru]-8, were designed and prepared. In particular, [Ru]-2 displayed extraordinary performance even in open air for the dehydrogenative coupling of alcohols and hydroxides. Notably, an unprecedentedly low catalyst loading of 250 ppm and the highest TON of 32 800 and TOF of 3200 until now were obtained.
Small “Yaw” Angles, Large “Bite” Angles and an Electron-Rich Metal: Revealing a Stereoelectronic Synergy To Enhance Hydride-Transfer Activity
Semwal, Shrivats,Mukkatt, Indulekha,Thenarukandiyil, Ranjeesh,Choudhury, Joyanta
supporting information, p. 13051 - 13057 (2017/09/26)
Cyclometalated complexes are an important class of (pre)catalysts in many reactions including hydride transfer. The ring size of such complexes could therefore be a relevant aspect to consider while modulating their catalytic activity. However, any correl
C^C* cyclometalated platinum(II) NHC complexes with β-ketoimine ligands
Tronnier, Alexander,Poethig, Alexander,Herdtweck, Eberhardt,Strassner, Thomas
, p. 898 - 908 (2014/03/21)
C^C* cyclometalated platinum(II) NHC complexes with chelating acetylacetonate ligands have been recently shown to be an interesting class of phosphorescent emitters. We sought to clarify the role of the acetylacetonate ligand by replacing one of the coord
