126614-95-7

Basic information

• Product Name: 3',4',4-Trichloroazoxybenzene
• Synonyms: 3',4',4-Trichloroazoxybenzene
• CAS NO: 126614-95-7
• Molecular Weight: 301.559
• Mol File: 126614-95-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3',4',4-Trichloroazoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 3',4',4-Trichloroazoxybenzene(126614-95-7)
• EPA Substance Registry System: 3',4',4-Trichloroazoxybenzene(126614-95-7)

Safety Data

• Hazardous Substances Data: 126614-95-7(Hazardous Substances Data)

Upstream product

• 67083-42-5 3,4-Dichloronitrosobenzene 
• 116278-63-8 N-(4-chlorophenyl)-O-pivaloylhydroxylamine 
• 33175-34-7 N-(3,4-dichlorophenyl)-hydroxylamine 
• 116278-64-9 C₁₁H₁₃Cl₂NO₂ 
• 823-86-9 N-(4-chlorophenyl)hydroxylamine 
• 635-21-2 5-chloroanthranilic acid 
• 126614-93-5 3',4',4-Trichloroazobenzene-2-carboxylic Acid 
• 126614-94-6 3',4',4-Trichloroazoxybenzene-2-carboxylic Acid 

Relevant articles and documents

Competitive Base-Induced α-Elimination and Methanolysis of N-Aryl-O-pivaloylhydroxylamines

The N-aryl-O-pivaloylhydroxylamines 1a-c are quite stable in MeOH under neutral conditions, but under mildly basic conditions (0.05 M Et2NH or Et3N) they undergo rapid decomposition (t1/2 = ca. 3-5 h at 25 deg C) by two competitive processes: apparent α-elimination to generate the nitrenes 2a-c and pivalic acid and basic ester methanolysis to generate the hydroxylamines 3a-c and methyl pivalate.The nitrenes decompose into the corresponding anilines 5 and azobenzenes 7, while the hydroxylamines undergo nitrene-mediated oxidation into the corresponding azoxybenzenes 6.The mechanism of this latter process was probed by addition of excess hydroxylamine, and a mechanism for the oxidation consistent with available data (Scheme II) is proposed.It was also found that the nitrosobenzenes 8 undergo nucleophilic attack by conjugate bases 4a-c of the title compounds to produce one of the two possible isomeric nonsymmetrical azoxybenzenes.