Tetrahedron Letters p. 3765 - 3768 (1989)
Update date:2022-08-02
Topics:
Schoenen, Frank J.
Porco, John A.
Schreiber, Stuart L.
VanDuyne, Gregory D.
Clardy, Jon
The synthesis and crystallographic analysis of a bicyclic core related to the esperamicin/calichemicin aglycones is reported.A key reaction involves the skeletal rearrangement of a mesylate derived from a type II Diels-Alder cycloadduct.
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