1266317-72-9Relevant academic research and scientific papers
Cesium-catalyzed highly regioselective synthesis of (Z)-vinylic selenosulfides via thioselenation of alkynes with unsymmetrical diorganoyl dichalcogenides
Peng, Lifen,Li, Rongzhen,Tang, Zilong,Chen, Jingyang,Yi, Rongnan,Xu, Xinhua
, p. 3099 - 3105 (2017/05/08)
A novel one-pot approach for the synthesis of (Z)-vinylic selenosulfides is demonstrated through the thioselenation of a wide range of alkynes with unsymmetrical diorganoyl dichalcogenides (RSSePh) catalyzed by cesium hydroxide monohydrate, avoiding the use of the transition metal catalyst and the previous preparation of chalcogen alkynes. Other outstanding features include mild reaction conditions, high regio- and stereo-selectivity, excellent yields and wide functional group tolerance.
Cesium-Catalyzed Regioselective Synthesis of Trisubstituted Heteroatom Alkenes: A New Strategy for the Preparation of Functional Alkenes
Chen, Jinyang,Tang, Zhi,Qiu, Renhua,He, Yunhua,Wang, Xie,Li, Ningbo,Yi, Haibo,Au, Chak-Tong,Yin, Shuang-Feng,Xu, Xinhua
supporting information, p. 2162 - 2165 (2015/05/13)
A highly chemo-, regio-, and stereoselective method for the synthesis of (Z)-vinylic selenosulfides and (Z)-vinylic tellurosulfides in a one-pot reaction of terminal alkynes, diaryl disulfides, and diaryl diselenides (ditellurides) catalyzed by simple bas
Highly stereoselective method to prepare bis-phenylchalcogen alkenes via addition of chalcogenolate to phenylseleno alkynes
Perin, Gelson,Borges, Elton L.,Alves, Diego
experimental part, p. 2066 - 2069 (2012/07/14)
The preparation of bis-phenylchalcogen alkenes starting from phenylseleno alkynes is described. The nucleophilic species of selenium, tellurium and sulfur were generated in situ from the reaction of the respective diphenyl dichalcogenide with NaBH4 in PEG-400 as solvent. The chalcogenolate anions were efficiently and selectively added to a variety of phenylselenoalkynes at mild conditions, furnishing the respective (Z)-1,2-bis-phenylchalcogen alkenes in good yields.
Cesium hydroxide-catalyzed hydrothiolation of alkynyl selenides to highly stereo- and regioselectively synthesize (Z)-1-organoseleno-2-arylthio-1-alkenes
Yu, Ai He,Qiu, Ren Hua,Tan, Nian Yuan,Peng, Li Feng,Xu, Xin Hua
experimental part, p. 687 - 690 (2012/01/05)
In the presence of catalytic amount of cesium hydroxide the hydrothiolation of alkynyl selenides occurred at room temperature in DMF under nitrogen atmosphere to give exclusive (Z)-1-organoseleno-2-arylthio-1-alkene in excellent yields. It could provide a
