28622-58-4Relevant articles and documents
Thorium Cubanes-Synthesis, Solid-State and Solution Structures, Thermolysis, and Chalcogen Exchange Reactions
Ringgold, Marissa,Rehe, David,Hrobárik, Peter,Kornienko, Anna Y.,Emge, Thomas J.,Brennan, John G.
, p. 7129 - 7141 (2018)
Thorium cubanes (py)8Th4(μ3-E′)4(μ2-EPh)4(ν-EPh)4 (E, E′ = S, Se) were prepared from ligand-based redox reactions of elemental E′ with Th(EPh)4. Products with all four
A novel synthesis of selenosulfides from diselenides by samarium diiodide
Guo,Zhang
, p. 374 - 375 (2007/10/03)
Diselenides were reduced by samarium diiodide in tetrahydrofuran (THF) to produce samarium selenolate. This selenolate anion reacted smoothly with sodium alkyl thiosulfates and phenylsulfenyl chloride to give selenosulfides in moderate to good yields.