1266332-44-8

Basic information

• Product Name: C₃H₂F₆O₂*C₁₁H₁₂N₂O
• Synonyms: C₃H₂F₆O₂*C₁₁H₁₂N₂O
• CAS NO: 1266332-44-8
• Molecular Weight: 372.267
• Mol File: 1266332-44-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃H₂F₆O₂*C₁₁H₁₂N₂O(CAS DataBase Reference)
• NIST Chemistry Reference: C₃H₂F₆O₂*C₁₁H₁₂N₂O(1266332-44-8)
• EPA Substance Registry System: C₃H₂F₆O₂*C₁₁H₁₂N₂O(1266332-44-8)

Safety Data

• Hazardous Substances Data: 1266332-44-8(Hazardous Substances Data)

Upstream product

• 684-16-2 Hexafluoroacetone 
• 215675-50-6 1,5-dimethyl-4-phenylimidazole 3-oxide 
• 25355-34-4 1-phenyl-propane-1,2-dione 1-oxime 

Relevant articles and documents

First synthesis of the N(1)-bulky substituted imidazole 3-oxides and their complexation with hexafluoroacetone hydrate

Synthesis of new 2-unsubstituted imidazole 3-oxides bearing bulky substituents at the N(1) atom, based on the condensation of appropriate alkylamines, formaldehyde, and corresponding a-(hydroxyimino)ketone, is described. Treatment of imidazole 3-oxides with hexafluoroacetone hydrate (HFAH) yields crystalline 1:1 complexes in nearly quantitative yields. Heating of isolated complexes possessing phenyl ring at the C(4) atom of imidazole ring, results in their isomerization into imidazol-2-ones in fair yields. The formation of analogous complexes of HFAH with other azole N-oxides is also described. ARKAT-USA, Inc.