1266334-99-9Relevant academic research and scientific papers
A gold(i)-catalyzed intramolecular oxidation-cyclopropanation sequence of 1,6-enynes: A convenient access to [n.1.0]bicycloalkanes
Qian, Deyun,Zhang, Junliang
supporting information; experimental part, p. 11152 - 11154 (2011/11/06)
A gold(i)-catalyzed tandem oxidation/cyclopropanation reaction of 1,6-enynes with an external oxidant has been developed. This quite simple and rapid strategy will provide a safe, mild and versatile avenue to numerous carbo- and hetero [n.1.0]bicyclic frameworks.
Palladium-catalyzed tandem fluorination and cyclization of enynes
Peng, Haihui,Liu, Guosheng
, p. 772 - 775 (2011/04/24)
A novel palladium-catalyzed tandem fluorination and cyclization of enynes has been developed. A favorable cis-fluoropalladation is proposed as a key step to construct a vinyl-F bond, and the final Csp3-Pd bond is reduced by alcohol. This transf
