126689-00-7

Usage

Uses

2,2-Dimethylethenylboronic acid pinacol ester

Upstream product

• 3017-69-4 2-methyl-1-propenylbromide 
• 73183-34-3 bis(pinacol)diborane 
• 61676-62-8 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 38614-36-7 2-methylpropen-1-ylmagnesium bromide 
• 84224-48-6 (2-Methyl-1-propenyl)-nonafluorbutansulfonat 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 

Downstream Products

• 1234845-40-9 methyl 5-chloro-3-methoxy-2-(2-methylprop-1-en-1-yl)benzoate 
• 1260498-97-2 methyl 2-[2-(2-methylpropen-1-yl)benzyl]-4-oxopentanoate 
• 1391713-18-0 methyl 4-amino-3-(2-methylprop-1-enyl) benzoate 
• 41801-83-6 (±)-1-(4-chlorophenyl)-3-methylbut-3-en-1-ol 
• 153624-73-8 3-(2-methylprop-1-en-1-yl)aniline 
• 75625-99-9 2-(4'-<2-methyl-1-propenyl>phenyl)propanoic acid 
• 5916-22-3 p-methyl-β,β-dimethylstyrene 

Relevant academic research and scientific papers

Palladium-catalyzed cross-coupling reaction of bis(pinacolato)diboron with 1-alkenyl halides or triflates: Convenient synthesis of unsymmetrical 1,3-dienes via the borylation-coupling sequence

The synthesis of 1-alkenylboronic acid pinacol esters via a palladium-catalyzed cross-coupling reaction of bis(pinacolato)diboron (pin2B2, pin = Me4C2O2) with 1-alkenyl halides or triflates was carrie

Synthesis of 1-alkenylboronic esters via palladium-catalyzed cross-coupling reaction of bis(pinacolato)diboron with 1-alkenyl halides and triflates

The synthesis of 1-alkenylboronic acid pinacol esters via the palladium-catalyzed cross-coupling reaction of 1-alkenyl halides or triflates with bis(pinacolato)diboron [(Me4C2O2)B-B(O2C2Me 4/sub

Substituted Tetraethynylethylene–Tetravinylethylene Hybrids

A general synthetic approach to molecular structures that are hybrids of tetraethynylethylene (TEE) and tetravinylethylene (TVE) is reported. The synthesis permits the controlled preparation of many previously inaccessible structures, including examples w

Enantioselective Conjunctive Cross-Coupling of Bis(alkenyl)borates: A General Synthesis of Chiral Allylboron Reagents

Palladium-catalyzed conjunctive cross-coupling is used for the synthesis of enantioenriched allylboron reagents. This reaction employs nonsymmetric bis(alkenyl)borates as substrates and appears to occur by a mechanism that involves selective activation of the less substituted alkene followed by migration of the more substituted alkene during the course of a Pd-induced metalate rearrangement.

Pyrrolidinobenzoic acid inhibitors of influenza virus neuraminidase: The hydrophobic side chain influences type A subtype selectivity

Neuraminidase (NA) plays a critical role in the life cycle of influenza virus and is a target for new therapeutic agents. A series of influenza neuraminidase inhibitors with the pyrrolidinobenzoic acid scaffold containing lipophilic side chains at the C3 position have been synthesized and evaluated for influenza neuraminidase inhibitory activity. The size and geometry of the C3 side chains have been modified in order to investigate structure-activity relationships. The results indicated that size and geometry of the C3-side chain are important for selectivity of inhibition against N1 versus N2 NA, important type A influenza variants that infect man, including the highly lethal avian influenza.

Highly substituted benzannulated cyclooctanol derivatives by samarium diiodide-induced cyclizations

A series of γ-oxo esters suitably substituted with various styrene subunits was subjected to samarium diiodide-induced 8-endo-trig cyclizations. Efficacy, regioselectivity and stereoselectivity of these reactions via samarium ketyls strongly depend on the