126754-60-7Relevant academic research and scientific papers
Glyoxylate-ene reaction catalyzed by Ln(OTf)3
Qian, Changtao,Huang, Taisheng
, p. 6721 - 6724 (1997)
Yb(OTf)3 can catalyze the glyoxylate-ene reaction effectively as a water-stable and reusable catalyst. Moreover, the selectivity of DA product or ene product can be adjusted by solvents in the reaction of glyoxylates with a diene (isoprene). In
Asymmetric Catalysis by a New Type of Chiral Binaphthol-Titanium Complex
Kitamoto, Dai,Imma, ironori,Nakai, Takeshi
, p. 1861 - 1864 (2007/10/02)
A new type of chiral 1,1'-bi-2-naphthol (BINOL)-derived titanium complex, prepared via complete hydrolysis of the complex formed in situ by mixing (i-PrO)4Ti and (R) -BINOL followed by azeotrope, serves as an efficient and moisture-tolerable enantioselect
Chiral titanium complex-catalyzed carbonyl-ene reaction with glyoxylate: Remarkable positive nonlinear effect
Mikami, Koichi,Terada, Masahiro
, p. 5671 - 5680 (2007/10/02)
The enantioselective glyoxylate-ene reaction catalyzed by chiral titanium complex derived from partially resolved binaphthol (BINOL) is shown to exhibit a remarkable level of asymmetric amplification (positive nonlinear effect). Thus, the optical yield of
Remarkable Positive Nonlinear Effect in the Enantioselective Glyoxylate-Ene Reaction Catalysed by a Chiral Titanium Complex
Terada, Masahiro,Mikami, Koichi,Nakai, Takeshi
, p. 1623 - 1624 (2007/10/02)
The enantioselective glyoxylate-ene reaction catalysed by chiral titanium complex derived from partially resolved BINOL is found to exhibit a remarkable level of asymmetric amplification, wherein the optical yield of the product significantly exceeds the
