1267635-98-2Relevant academic research and scientific papers
Diastereoselective carbometalation of Oxa- and azabicyclic alkenes under iron catalysis
Ito, Shingo,Itoh, Takuma,Nakamura, Masaharu
supporting information; experimental part, p. 454 - 457 (2011/03/16)
Highly diastereoselective carbometalation of oxa- and azabicyclic alkenes with arylzinc reagents has been achieved by using FeCl3 and novel ortho-phenylene diphosphine ligands (see scheme; E=electrophile). The carbozincation products are stable towards β-heteroatom elimination and can be trapped with various electrophiles.
