126769-32-2Relevant academic research and scientific papers
OXIDATION OF ALKENES BY A CHIRAL NON-PORPHYRINIC OXIDIZING CATALYST BASED ON THE BLEOMYCIN-Fe(II) COMPLEX
Suga, Akira,Sugiyama, Toru,Otsuka, Masami,Ohno, Masaji,Sugiura, Yukio,Maeda, Kenji
, p. 1191 - 1204 (2007/10/02)
A synthetic model for the metal binding site of bleomycin with 4-dimethylaminopyridine nucleus, namely PYML-8, shows dioxygen activation up to 125percent of that of bleomycin. β-Methylstyrene is oxidized with the Fe(III)-H2O2, Fe(III)-PhIO, or Fe(II)-O2 complex systems of PYML-8 to give a set of products including optically active epoxide.The product composition is dependent on iron, oxygen source, and reducing agent employed, suggesting varied active species generated from each complex system.
