126784-52-9

Upstream product

• 1655-07-8 ethyl 2-oxocyclohexane carboxylate 
• 66088-37-7 ethyl 1-methyl-2-oxocyclohexancarboxylate 
• 74-88-4 methyl iodide 
• 126685-44-7 6-ethoxycarbonyl-2,6-dimethyl-1-cyclohexenyl acetate 

Downstream Products

• 126784-54-1 6-ethoxycarbonyl-2,6-dimethyl-1-cyclohexenyl acetate 
• 126784-56-3 (2R,6S)-2-ethoxycarbonyl-2,6-dimethylcyclohexanone 
• 25914-37-8 (2R,6R)-2-ethoxycarbonyl-2,6-dimethyl-1-phenylethynylcyclohexan-1-ol 
• 25914-41-4 (2R,6R)-2-ethoxycarbonyl-2,6-dimethyl-1-phenylethylcyclohexan-1-ol 
• 126784-55-2 (2R,6R)-2-ethoxycarbonyl-2,6-dimethylcyclohexanone 
• 125676-89-3 (1R*,2S*,6S*)-2-hydroxymethyl-2,6-dimethylcyclohexan-1-ol 
• 126685-44-7 6-ethoxycarbonyl-2,6-dimethyl-1-cyclohexenyl acetate 

Relevant academic research and scientific papers

Total Synthesis of (±)-Waihoensene

The first total synthesis of waihoensene, a tetracyclic diterpene containing an angular triquinane and a six-membered ring, with four contiguous quaternary carbon atoms, was achieved through the tandem cycloaddition reaction of an allenyl diazo substrate containing a six-membered ring via trimethylenemethane (TMM) diyl intermediate.

A SYNTHESIS OF (-)-DEOXYPODOCARPIC ACID METHYL ESTER VIA AN ENZYMATIC ENANTIOSELECTIVE HYDROLYSIS OF THE KEY INTERMEDIATE ENOL ESTER

(1R,4aR,10aS)-(-)-1-Methoxycarbonyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthrene (deoxypodocarpic acid methyl ester 1), a useful intermediate for the synthesis of various diterpenes, was synthesized from (R)-(+)-6-ethoxycarbonyl-2,6-dimethyl-1-