126784-53-0Relevant articles and documents
Total Synthesis of (±)-Waihoensene
Lee, Hongsoo,Kang, Taek,Lee, Hee-Yoon
, p. 8254 - 8257 (2017)
The first total synthesis of waihoensene, a tetracyclic diterpene containing an angular triquinane and a six-membered ring, with four contiguous quaternary carbon atoms, was achieved through the tandem cycloaddition reaction of an allenyl diazo substrate containing a six-membered ring via trimethylenemethane (TMM) diyl intermediate.
A SYNTHESIS OF (-)-DEOXYPODOCARPIC ACID METHYL ESTER VIA AN ENZYMATIC ENANTIOSELECTIVE HYDROLYSIS OF THE KEY INTERMEDIATE ENOL ESTER
Sugai, Takeshi,Kakeya, Hideaki,Ohta, Hiromichi,Morooka, Mitsuo,Ohba, Shigeru
, p. 6135 - 6144 (2007/10/02)
(1R,4aR,10aS)-(-)-1-Methoxycarbonyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthrene (deoxypodocarpic acid methyl ester 1), a useful intermediate for the synthesis of various diterpenes, was synthesized from (R)-(+)-6-ethoxycarbonyl-2,6-dimethyl-1-