126814-16-2

Upstream product

• 17793-95-2 cis-1,2-dihydrocatechol 
• 941-69-5 N-phenyl-maleimide 
• 80409-75-2 cis-2,2-dimethyl-3a,7a-dihydrobenzo[1,3]dioxole 

Downstream Products

• 126814-12-8 (3aα,4α,7α,7aα,8S*,9R*)-3a,4,7,7a-tetrahydro-8,9-dihydroxy-2-phenyl-4,7-ethano-1H-isoindole-1,3(2H)-dione 
• 126814-14-0 (3aα,4α,7α,7aα,8S*,9R*)-3a,4,7,7a-tetrahydro-2-phenyl-8,9-bis<(trimethylsilyl)oxy>-4,7-ethano-1H-isoindole-1,3(2H)-dione 
• 126814-13-9 (3aα,4α,7α,7aα,8S*,9R*)-8,9-bis(acetyloxy)-3a,4,7,7a-tetrahydro-2-phenyl-4,7-ethano-1H-isoindole-1,3(2H)-dione 
• 144562-51-6 (2α,3aβ,4β,4aα,7aα,8β,8aβ)-4a,7a,8,8a-tetrahydro-2,6-diphenyl-4,8-etheno-4H-1,3-dioxolo<4,5-f>isoindole-5,7(3aH,6H)-dione 
• 126814-15-1 (3aα,4α,4aβ,7aβ,8α,8aα)-4a,7a,8,8a-tetrahydro-2,2-dimethyl-6-phenyl-4,8-etheno-4H-1,3,2-dioxasilolo<4,5-f>isoindole-5,7(3aH,6H)-dione 
• 144562-46-9 (3aα,4α,7α,7aα,8S*,9R*)-3a,4,7,7a-tetrahydro-8,9-dimethoxy-2-phenyl-4,7-ethano-1H-isoindole-1,3(2H)-dione 

Relevant academic research and scientific papers

?-Facial diastereoselectivity in the Diels-Alder reactions of cis-cyclohexa-3,5-diene-1,2-diol and derivatives with N-phenylmaleimide

N-Phenylmaleimide undergoes Diels-Alder cycloaddition predominantly to the face of cis-cyclohexa-2,4-diene-1,2-diol (3) syn to the oxygen functions.Derivatization can be used to alter the ?-facial diastereoselectivity in a synthetically useful manner.The

, , and Carbene Addition Reactions Involving Cyclohexa-3,5-diene-cis-1,2-diol Derivatives

The reactions of cis-1,2-isopropylidenedioxycyclohexa-3,5-diene (1) with two N-substituted maleimides, diphenylketene, dichlorocarbene and ethoxycarbonylcarbene are described.Selected reactions of the 3-trifluoromethyl- (2) and 3-fluoro- (3) analogues with these reagents are also reproted.