1268492-53-0Relevant articles and documents
Enantioselective synthesis of Axially chiral hydroxy carboxylic acid derivatives by rhodium-catalyzed [2 〈 2 〈 2] cycloaddition
Ogaki, Shuichiro,Shibata, Yu,Noguchi, Keiichi,Tanaka, Ken
, p. 1926 - 1929 (2011)
Axially chiral hydroxy carboxylic acid derivatives were successfully synthesized with high yields and ee values by the cationic rhodium(I)/axially chiral biaryl bisphosphine complex-catalyzed enantioselective [2 〈 2 〈 2] cycloaddition. Axially chiral hydroxy and dihydroxy carboxylic acid derivatives, bearing the aryl group at the ortho-position of the alkoxycarbonyl group, were also synthesized with high regio- and enantioselectivity.