1268600-40-3

Upstream product

• 1268600-51-6 (4S)-3-[(2R,3S)-3-tert-butyldimethylsilyloxy-2-[(benzyloxy)-methyl]pent-4-en-oyl]-4-isopropyl-1,3-thiazolidine-2-thione 

Downstream Products

• 1268600-41-4 (2R,3S)-2-(benzyloxy)methyl-1-bromo-3-(tert-butyldimethylsilyloxy)hex-5-en-1-yne 
• 1268600-44-7 (3R,4S)-N-(tert-butoxycarbonyl)-N-(2-propenyl)hex-5-en-3-(benzyloxymethyl)-4-(tert-butyldimethylsilanyloxy)-1-ynylamine 
• 1268600-47-0 (3R,4S)-N-(2-trimethylsilylethoxycarbonyl)-N-(2-propenyl)-hex-5-en-3-benzyloxymethyl-4-(tert-butyldimethylsilanyloxy)-1-ynylamine 
• 1268600-45-8 N-allyl-N-(tert-butoxycarbonyl)-2-[(1R,2S)-1-(benzyloxy)methyl-2-(tert-butyldimethylsilanyloxy)but-3-enyl]-3-hydroxy-5-(methoxymethoxy)methylphenylamine 

Relevant academic research and scientific papers

Synthesis of polycyclic benzofused nitrogen heterocycles via a tandem ynamide benzannulation/ring-closing metathesis strategy. Application in a formal total synthesis of (〈)-FR900482

A two-stage "tandem strategy" for the synthesis of benzofused nitrogen heterocycles is described that is particularly useful for the construction of systems with a high level of substitution on the benzenoid ring. The first stage in the strategy involves