1268600-47-0

Upstream product

• 279257-13-5 2-(trimethylsilyl)ethyl allylcarbamate 
• 1268600-41-4 (2R,3S)-2-(benzyloxy)methyl-1-bromo-3-(tert-butyldimethylsilyloxy)hex-5-en-1-yne 
• 1268600-51-6 (4S)-3-[(2R,3S)-3-tert-butyldimethylsilyloxy-2-[(benzyloxy)-methyl]pent-4-en-oyl]-4-isopropyl-1,3-thiazolidine-2-thione 
• 1268600-40-3 (2R,3S)-2-(benzyloxy)methyl-3-(tert-butyldimethylsilybutyldimethylsilyloxy)pent-4-en-al 
• 2916-68-9 2-(Trimethylsilyl)ethanol 

Downstream Products

• 1268600-48-1 N-allyl-N-(2-trimethylsilanyloxycarbonyl)-2-(1R,2S)-[1-(benzyloxy)methyl-2-(tert-butyldimethylsilanyloxy)but-3-enyl]-3-hydroxy-5-(benzyloxy)methylphenylamine 

Relevant academic research and scientific papers

Synthesis of polycyclic benzofused nitrogen heterocycles via a tandem ynamide benzannulation/ring-closing metathesis strategy. Application in a formal total synthesis of (〈)-FR900482

A two-stage "tandem strategy" for the synthesis of benzofused nitrogen heterocycles is described that is particularly useful for the construction of systems with a high level of substitution on the benzenoid ring. The first stage in the strategy involves