1268720-10-0Relevant academic research and scientific papers
Kinetic resolution of activated nitroallylic acetates with aldehydes and ketones through a conjugate addition-elimination SN2′ process
Jannapu Reddy, Raju,Lee, Pei-Hsun,Magar, Dhananjay R.,Chen, Jung-Hsuan,Chen, Kwunmin
experimental part, p. 353 - 365 (2012/02/04)
A unique organocatalytic kinetic resolution (KR) of nitroallylic acetates has been developed. A variety of racemic nitroallylic acetates (1a-n) were resolved with chiral enamines formed in situ from the reaction of aldehydes and ketones with organocatalys
Highly efficient organocatalytic kinetic resolution of activated nitroallylic acetates with aldehydes via conjugate addition-elimination
Reddy, Raju Jannapu,Chen, Kwunmin
supporting information; experimental part, p. 1458 - 1461 (2011/05/15)
A novel, efficient, and unprecedented organocatalytic kinetic resolution has been developed. For the first time, a variety of nitroallylic acetates 1a-i have been resolved with aldehydes in the presence of 2 (2.5 mol %) via conjugate addition-elimination.
