126910-37-0

Basic information

• Product Name: Benzene, (2,3,4,5-tetramethyl-1,3-cyclopentadien-1-yl)-
• CAS NO: 126910-37-0
• Molecular Formula: C15H18
• Molecular Weight: 198.308
• Mol File: 126910-37-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, (2,3,4,5-tetramethyl-1,3-cyclopentadien-1-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (2,3,4,5-tetramethyl-1,3-cyclopentadien-1-yl)-(126910-37-0)
• EPA Substance Registry System: Benzene, (2,3,4,5-tetramethyl-1,3-cyclopentadien-1-yl)-(126910-37-0)

Safety Data

• Hazardous Substances Data: 126910-37-0(Hazardous Substances Data)

Upstream product

• 54458-61-6 2,3,4,5-tetramethyl-2-cyclopenten-1-one 
• 591-51-5 phenyllithium 
• 503-17-3 dimethylacetylene 
• 100-52-7 benzaldehyde 
• 108-86-1 bromobenzene 

Downstream Products

• 926294-24-8 dichloro(tetramethylcyclopentadienylbenzene)rhodium(III)dimer 
• 1292280-39-7 dichloro(tetramethylcyclopentadienylbenzene)iridium(III)dimer 
• 1147742-75-3 [η5-phenyltetramethylcyclopentadienyl)La(N(SiHMe2)2)2] 

Relevant articles and documents

Lewis acid mediated reactions of zirconacyclopentadienes with aldehydes: One-pot synthetic route to indene and cyclopentadiene derivatives from aldehydes and benzyne or alkynes

One-pot procedures for the preparation of highly substituted indenes, tetrahydroindenes, and cyclopentadienes have been developed by using a combination of zirconocene-mediated C-C-bond-forming reactions with Lewis acid mediated activation of carbonyl groups. The carbonyl groups of aldehydes were deoxygenated in the reaction and behaved formally as a one-carbon unit. A variety of Lewis acids were checked and showed different reactivities in this reaction.

NOVEL IRIDIUM/RHODIUM ANTI-CANCER COMPOUNDS

The present invention relates to novel iridium and/or rhodium containing complexes for use as a cytotoxic, such as an anti-cancer agent. There is also provided a method of preparing said compounds.