126983-09-3Relevant academic research and scientific papers
4,5,6,11-tetrahydrobenzo [6,7] cycloocta [1,2-b]thiophen-6,11-imines and 6,11-dihydrobenzo [6,7] cycloocta [1,2-b] thiophen-6,11-imines
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, (2008/06/13)
The present invention relates to compounds of the formula STR1 wherein the broken line represents a saturated or an olefinic bond, R1 and R4 are each hydrogen or C1 to C6 alkyl, and R2 and R3/su
A NOVEL REARRANGEMENT FORMING 4,5,6,11-TETRAHYDROBENZOCYCLOOCTATHIOPHEN-6,11-IMINES
Robinson, Ralph P.,Donahue, Kathleen M.,Saccomano, Nicholas A.
, p. 5203 - 5206 (2007/10/02)
Exposure of the spirocyclic isoindolines 9 and 16 and the spirocyclic ether 23 to HBr gas in methylene chloride at 0 deg C leads to the formation of the bridged heterocycles 10, 17, and 24 respectively.These novel rearrangements probably occur via retro-M
