1269844-96-3Relevant academic research and scientific papers
Facile rotation around a silicon-phosphorus double bond enabled through coordination to tungsten
Breit, Nora C.,Szilvási, Tibor,Inoue, Shigeyoshi
, p. 11272 - 11275 (2015)
Unprecedented E/Z isomerisation of a SiP bond was observed by temperature dependent NMR spectroscopy. DFT calculations showed that the coordination of phosphasilene to tungsten lowered the rotational barrier from 19.1 to 14.2 kcal mol-1. The th
An ylide-like phosphasilene and striking formation of a 4π-electron, resonance-stabilized 2,4-disila-1,3-diphosphacyclobutadiene
Inoue, Shigeyoshi,Wang, Wenyuan,Praesang, Carsten,Asay, Matthew,Irran, Elisabeth,Driess, Matthias
supporting information; experimental part, p. 2868 - 2871 (2011/04/19)
The first N-donor-stabilized phosphasilene LSi(SiMe3)=PSiMe 3 (L = PhC(NtBu)2) has been synthesized in 87% yield through 1,2-silyl migration of the (Me3Si)2P-substituted, N-heterocyclic silylene [LSi-
