127032-93-3Relevant academic research and scientific papers
Inverse electron demand Diels-Alder reactions of N-sulfonyl α,β-unsaturated imines: A general approach to implementation of the 4π participation of 1-aza-1,3-butadienes in Diels-Alder reactions
Boger, Dale L.,Corbett, Wendy L.,Curran, Timothy T.,Kasper
, p. 1713 - 1729 (2007/10/02)
Full details of a study of the inverse electron demand Diels-Alder reactions of W-sulfonyl-1 -aza-1,3-tmtadienes are described. The α,β-unsaturated N-sulfonylimines proved accessible through clean, homolytic rearrangement of in situ generated oxime O-sulf
Room Temperature, Endo-Specific 1-Aza-1,3-butadiene Diels-Alder Reactions: Acceleration of the LUMOdiene-Controlled Cycloaddition Reactions through Noncomplementary Azadiene Substitution
Boger, Dale L.,Corbett, Wendy L.,Wiggins, J. Mark
, p. 2999 - 3000 (2007/10/02)
A preparation of N-sulfonyl-2-(ethoxycarbonyl)-1-aza-1,3-butadienes 5-6 is described and is based on the use of the stabilized Wittig reagent 1 and implementation of a subsequent room temperature, in situ homolytic oxime O-sulfinyl to N-sulfonyl rearrange
