127082-47-7

Upstream product

• 6630-99-5 1,2,3,4-thiatriazole-5-amine 
• 1005-56-7 phenylcarbonochloridothioate 
• 130255-54-8 5-Phenoxy-[1,2,4]dithiazol-3-ylideneamine; hydrochloride 

Downstream Products

• 127082-50-2 (6-Phenoxy-4λ⁴-[1,2,4]dithiazolo[1,5-b][1,2,4]dithiazol-2-yl)-phenyl-amine 
• 159762-85-3 N,N'-Bis(5-phenoxy-3,3aλ⁴,4-trithia-1,6-diazapentalen-2-yl)-4,4'-(1,3-propandiyl)dipiperidin 
• 159762-82-0 2,17-Bis(5-phenoxy-3,3aλ⁴,4-trithia-1,6-diazapentalen-2-yl)-5,8,11,14-tetraoxa-2,17-diazaoctadecan 
• 159762-84-2 3,18-Bis(5-phenoxy-3,3aλ⁴,4-trithia-1,6-diazapentalen-2-yl)-6,9,12,15-tetraoxa-3,18-diazaeicosan 
• 164922-17-2 7,16-Bis(5-phenoxy-1,6,6aλ⁴-trithia-3,4-diazapentalen-2-yl)-1,4,10,13-tetraoxa-7,16-diazacyclooctadecan 
• 155876-15-6 2-(4-Nitrophenylhydrazino)-5-phenoxy-1,6,6aλ⁴-trithia-3,4-diazapentalen 
• 155876-12-3 5-phenoxy-2-phenylhydrazino-1,6,6aλ⁴-trithia-3,4-diazapentalen 

Relevant academic research and scientific papers

Thiatriazoles. VII. 3-Aroxy-1,2,4-dithiazole-5-imids of 5-Amino-1,2,3,4-thiatriazole

The unstable but isolable 3-aroxy-1,2,4-dithiazole-5-imids (2a-d) has been found on chlorothioformate acylation of 5-amino-1,2,3,4-thiatriazole (1) in acetonitril.Further acylation and nucleophilic displacement reactions gave stable 3-amino-5-acylimino-1,2,4-dithiazoles (6a-c, 7).The structure of the prepared compounds was inferred from their (1)H and (13)C-n.m.r., mass spectra and corroborated by comparison with the data of similar derivatives as well as by chemical means.

5-Amino-1,2,3,4-thiatriazole: Its Acylation with Chloroformates and Chlorothioformates as a Route to 1,2,4-Thiadiazoles and 1,6,6a,Δ4-Trithia-3,4-diazapentalenes

Pyridine catalyzed acylation of 5-amino-1,2,3,4-thiatriazole with chloroformates and chlorothioformates afforded 3,5-bis(ethoxycarbonylamino)-1,2,4-thiadiazoles in the former and 2,5-bis(phenoxy)-1,6,6a,Δ4-trithia-3,4-diazapentalenes in the lat