159762-85-3Relevant academic research and scientific papers
Aminolysis of 2,5-Bis(aryloxy)-3,3aλ4,4-trithia-1,6-diazapentalenes - an Entry to Macrocyclic Heteropentalenes
Tittelbach, Franz,Lutze, Gerhard,Graubaum, Heinz
, p. 2209 - 2214 (2007/10/02)
The N,N'-bis(3,3aλ4,4-trithia-1,6-diazapentalenyl)diamines 6, 7 and azacrown ethers 8, incorporating two sulfur-containing diazapentalenes, have been synthesized from 2,5-bis(aryloxy)-3,3aλ4,4-trithia-1,6-diazapentalenes 1 and diamines.The aminolysis of 1 with amines has also been studied providing 2-monoamino- 3 and 2,5-diaminoheteropentalenes 4. - Key Words: Macrocycles / Azacrown ethers / Pentalenes, 2,5-diamino-3,3aλ4,4-trithia-1,6-diaza-
