127099-06-3Relevant academic research and scientific papers
Nickel(II)-Nickel(II) Azadithiolates: Synthesis, Structural Characterization, and Electrocatalytic H2Production
Song, Li-Cheng,Liu, Wen-Bo,Liu, Bei-Bei
, p. 1431 - 1439 (2020)
Azadithiolato-bridged dinuclear Ni2 complexes with the general formula [(η5-C5H5)Ni{(μ-SCH2)2NC6H4R-4}Ni(diphos)]BF4 (8-11, R = H, Cl, MeO; diphos = dppv, dppe) have been prepared by a well-designed synthetic method including the following three separate
N-Substituted Derivatives of the Azadithiolate Cofactor from the [FeFe] Hydrogenases: Stability and Complexation
Angamuthu, Raja,Chen, Chi-Shian,Cochrane, Tyler R.,Gray, Danielle L.,Schilter, David,Ulloa, Olbelina A.,Rauchfuss, Thomas B.
, p. 5717 - 5724 (2015)
Experiments are described that probe the stability of N-substituted derivatives of the azadithiolate cofactor recently confirmed in the [FeFe] hydrogenases (Berggren, G., et al. Nature 2013, 499, 66). Acid-catalyzed hydrolysis of bis(thioester) BnN(CHsub
Syntheses of optically active γ-ketothiols and the esters by lipase-catalyzed hydrolysis via α-acetylthiomethylation of ketones
Izawa, Tomohiko,Terao, Yoshiyasu,Suzuki, Kunio
, p. 2645 - 2648 (2007/10/03)
The α-acetylthiomethylation of ketones was achieved by the reaction of ketones or the enamines with N,N-bis-(acetylthiomethyl)-p-chloroaniline in the presence of trifluoroacetic acid. The resulting thiolesters were hydrolyzed enantioselectively by catalys
