1271-29-0Relevant articles and documents
The reaction of titanocene bis(ferrocenylacetylide) and bis(ruthenocenylacetylide) with silver cation: Formation of bis(Ti-tweezers) silver complexes
Hayashi, Yukiko,Osawa, Masahisa,Kobayashi, Kimiko,Sato, Takuma,Sato, Masaru,Wakatsuki, Yasuo
, p. 169 - 175 (1998)
Titanocene bis(acetylide) where the acetylide has ferrocenyl or ruthenocenyl terminal group (C5H4R)2Ti{(CC)n-Mc}2, reacted with 0.5 equivalent amount of AgPF6 giving cationic heptanuclear c
Synthesis and characterization of Cp2Ti-containing organometallics via in situ oxidative-addition of 'Cp2Ti' intermediate
Song, Li-Cheng,Liu, Peng-Chong,Han, Cong,Hu, Qing-Mei
, p. 119 - 125 (2002)
A simple and convenient route for synthesizing Cp2 Ti-containing compounds (RS)2TiCp2 (1, R = 1-C10H7; 2, R = CH2=CHCH2; 3, R = n-C5H11; 4, R = CH2CO 2Me; 5, R = CH2CO2Et; 6, R = (η5-C5H5)Fe(η5 -C5H4CH2)) and [η2-OC(Ph) =C(Ph)O] TiCp2 (7) has been developed. This route starts from Cp2TiCl2 and involves an in situ oxidative-addition of the intermediate 'titanocene' with corresponding RSSR and benzil. While 7 was previously prepared by another route, 1-6 and one starting material [(η5-C5H5) Fe(η5-C5H4CH2)] 2S2 (8) are new and have been characterized by elemental analysis, IR and 1H-NMR spectroscopy, as well as by X-ray diffraction analysis for 1, 6 and 7. Furthermore, the electrochemical properties of 1-6 have been studied by cyclic voltammetry.
FORMATION REACTIVITIES, AND MOLECULAR STRUCTURES OF PHOSPHINE DERIVATIVES OF TITANOCENE - ISOLATION AND CHARACTERIZATION OF A TITANIUM MONOOLEFIN pi COMPLEX.
Edwards,Rogers,Sikora,Atwood,Rausch
, p. 416 - 426 (2007/10/02)
The synthesis of several new phosphine derivatives of titanocene under both thermally and photochemically induced conditions are described. The molecular structures of two of these complexes have been elucidated by means of single-crystal X-ray diffraction methods, and the bonding modes of the respective phosphine ligands to titanium are compared. Finally, the utility of the triethylphosphine analogue as a versatile intermediate for the generation of pi -acetylenic and pi -monoolefinic complexes of titanium is reported. Refs.