127106-17-6

Basic information

• Product Name: Carbonic acid 2-(3-benzyl-12-ethyl-4,16-dimethyl-2,5,11,14,18,21,24-heptaoxo-19-phenyl-17-oxa-1,4,10,13,20-pentaaza-tricyclo[20.4.0.0^6,10]hexacos-15-ylcarbamoyl)-pyridin-3-yl ester 2,2,2-trichloro-ethyl ester
• Synonyms: Carbonic acid 2-(3-benzyl-12-ethyl-4,16-dimethyl-2,5,11,14,18,21,24-heptaoxo-19-phenyl-17-oxa-1,4,10,13,20-pentaaza-tricyclo[20.4.0.0^6,10]hexacos-15-ylcarbamoyl)-pyridin-3-yl ester 2,2,2-trichloro-ethyl ester
• CAS NO: 127106-17-6
• Molecular Weight: 999.302
• Mol File: 127106-17-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Carbonic acid 2-(3-benzyl-12-ethyl-4,16-dimethyl-2,5,11,14,18,21,24-heptaoxo-19-phenyl-17-oxa-1,4,10,13,20-pentaaza-tricyclo[20.4.0.0^6,10]hexacos-15-ylcarbamoyl)-pyridin-3-yl ester 2,2,2-trichloro-ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonic acid 2-(3-benzyl-12-ethyl-4,16-dimethyl-2,5,11,14,18,21,24-heptaoxo-19-phenyl-17-oxa-1,4,10,13,20-pentaaza-tricyclo[20.4.0.0^6,10]hexacos-15-ylcarbamoyl)-pyridin-3-yl ester 2,2,2-trichloro-ethyl ester(127106-17-6)
• EPA Substance Registry System: Carbonic acid 2-(3-benzyl-12-ethyl-4,16-dimethyl-2,5,11,14,18,21,24-heptaoxo-19-phenyl-17-oxa-1,4,10,13,20-pentaaza-tricyclo[20.4.0.0^6,10]hexacos-15-ylcarbamoyl)-pyridin-3-yl ester 2,2,2-trichloro-ethyl ester(127106-17-6)

Safety Data

• Hazardous Substances Data: 127106-17-6(Hazardous Substances Data)

Upstream product

• 127106-16-5 Carbonic acid allyl ester 2-(3-benzyl-12-ethyl-4,16-dimethyl-2,5,11,14,18,21,24-heptaoxo-19-phenyl-17-oxa-1,4,10,13,20-pentaaza-tricyclo[20.4.0.0^6,10]hexacos-15-ylcarbamoyl)-pyridin-3-yl ester 
• 127092-11-9 3-(2,4-Dinitro-phenoxy)-pyridine-2-carboxylic acid (3-benzyl-12-ethyl-4,16-dimethyl-2,5,11,14,18,21,24-heptaoxo-19-phenyl-17-oxa-1,4,10,13,20-pentaaza-tricyclo[20.4.0.0^6,10]hexacos-15-yl)-amide 
• 668-72-4 virginiamycin S₁ 
• 17341-93-4 2,2,2-Trichloroethyl chloroformate 

Downstream Products

• 668-72-4 virginiamycin S₁ 
• 127106-18-7 Staphylomycin-S-saeure 
• 127092-15-3 2-(Methyl-{1-[2-(3-{2-[(4-oxo-piperidine-2-carbonyl)-amino]-2-phenyl-acetoxy}-2-{[3-(2,2,2-trichloro-ethoxycarbonyloxy)-pyridine-2-carbonyl]-amino}-butyrylamino)-butyryl]-pyrrolidine-2-carbonyl}-amino)-3-phenyl-propionic acid; compound with trifluoro-acetic acid 
• 127092-13-1 2-({1-[2-(2-[(3-Allyloxycarbonyloxy-pyridine-2-carbonyl)-amino]-3-{2-[(4-oxo-piperidine-2-carbonyl)-amino]-2-phenyl-acetoxy}-butyrylamino)-butyryl]-pyrrolidine-2-carbonyl}-methyl-amino)-3-phenyl-propionic acid; compound with trifluoro-acetic acid 
• 127106-16-5 Carbonic acid allyl ester 2-(3-benzyl-12-ethyl-4,16-dimethyl-2,5,11,14,18,21,24-heptaoxo-19-phenyl-17-oxa-1,4,10,13,20-pentaaza-tricyclo[20.4.0.0^6,10]hexacos-15-ylcarbamoyl)-pyridin-3-yl ester 
• 127092-08-4 3-(2-Oxo-2-phenyl-ethoxy)-pyridine-2-carboxylic acid (3-benzyl-12-ethyl-4,16-dimethyl-2,5,11,14,18,21,24-heptaoxo-19-phenyl-17-oxa-1,4,10,13,20-pentaaza-tricyclo[20.4.0.0^6,10]hexacos-15-yl)-amide 
• 127092-10-8 C₄₆H₅₀Cl₃N₇O₁₂ 
• 127092-09-5 C₅₁H₅₅N₇O₁₁ 

Relevant articles and documents

A SEARCH FOR PHENOLIC PROTECTION IN VIRGINIAMYCIN S

In order to be able to mask the hydroxyl grouping of the pipecolic acid residue in Virginiamycin during alkaline (NaOH) and acidic (Tfa) break-down procedures and to use peptidic fragments coming thereof for further reconstitution by classical peptide synthesis procedures, we have investigated several candidates for protection/deprotection.Thus the phenacyl derivatives (4 and 5), the allyloxycarbonyl derivative (6), the trichloroethyloxycarbonyl derivatives (8 and 9) and the 2,4-dinitrophenyl derivative (10) have been prepared.Among these none were stable in aqueous basic conditions.The Alloc- (6) the Troc- (8) and Dnp-derivative (10) may have some applications under acidic conditions.