127129-06-0Relevant academic research and scientific papers
Thermally induced cyclobutenone rearrangements and domino reactions
Harrowven, David C.,Pascoe, David D.,Guy, Ian L.
, p. 425 - 428 (2008/02/02)
(Chemical Equation Presented) Four thermal-rearrangement pathways and a domino reaction leading to quinones arise from the thermolysis of cyclobutenones. The course of vinylcyclobutenone rearrangements is dictated by the nature of the substituent, R (see
Kinetic resolution of racemic 2-substituted cyclohexanones by enantioselective deprotonation
Kim,Kawasaki,Nakajima,Koga
, p. 6537 - 6540 (2007/10/02)
Incomplete deprotonation of racemic 2-substituted cyclohexanones (dl-4) by chiral lithium amides (2) in the presence of trimethylsilyl chloride was found to give the corresponding trimethylsilyl enol ethers (5) and the unreacted ketones (4) in reasonably high enantiomeric excesses.
