127140-75-4Relevant academic research and scientific papers
NON CONCERTED PATHWAY IN THE GENERATION OF DEHYDROARENES BY THERMAL DECOMPOSITION OF DIARYLIODONIUM CARBOXYLATES.
Luis, S. V.,Gavina, F.,Ferrer, P.,Safont, V. S.,Torres, M. C.,Burguete, M. I.
, p. 6281 - 6296 (2007/10/02)
1,3-Dehydrobenzene, 1,4-dehydrobenzene and 2,3-dehydronaphthalene are generated in the thermal decomposition of appropriate diaryliodonium carboxylates as demonstrated by the use of the three phase test.Intermediate species C6H4CO2 for m- and p-benzyne and C10H6CO2 for 2,3-naphthalyne have been unambiguously trapped in the same way, showing how non-concerted processes are the main pathway for generation of arynic intermediates from those iodonium salts.
