127154-77-2Relevant academic research and scientific papers
The scope and limitations of 1,3-stannyl shift-promoted intramolecular cyclizations of α-stannyl radicals with a formyl group
Ueng, Shau-Hua,Chen, Ming-Jen,Chu, Shu-Fang,Shao, Yar-Fang,Fan, Gang-Ting,Chang, Sheng-Yueh,Tsai, Yeun-Min
, p. 1502 - 1512 (2006)
α-Tributylstannyl radicals can be generated from the corresponding bromides or xanthates. These radicals undergo efficient intramolecular 1,5-cyclizations with a formyl group. The resulting β-stannyl alkoxy radicals proceed through a 1,3-stannyl shift fro
Syntheses of Bicyclooctanes via Bifurcating Radical Cyclization Pathways
Nagai, Mitsuo,Lazor, Jerome,Wilcox, Craig S.
, p. 3440 - 3442 (2007/10/02)
The bifurcating cyclization pathways of radicals derived in a one-pot process from acyclic geminal dibromides efficiently afford bicyclooctane derivatives.
