1271726-69-2Relevant academic research and scientific papers
Chemoenzymatic total synthesis of cryptocaryalactone natural products
Reddy, Yarram Narasimha,Kumari, Tenkayala Navya,Thota, Pradeepkumar,Jyothi, Perla,Gupta, Ajay Kumar
, p. 160 - 162 (2018)
A new chemoenzymatic route for the preparation of cryptocaryalactones natural products using a kinetic resolution process as the key step is described. Novozyme-435 catalyzed hydrolysis of the prochiral (±)-monoester 7 afforded the precursors of cryptocar
An efficient and stereoselective synthesis of obolactone via modified Evans' Aldol protocol
Kumar, Rayala Naveen,Meshram
, p. 5547 - 5551 (2017)
Stereocontrolled total synthesis of obolactone was achieved from trans-cinnamaldehyde. The key steps in this synthetic sequence are a asymmetric Mukaiyama Aldol, a Crimmins' modified Evans' Aldol reaction to introduce C2′ stereocentre, a nucleophilic addi
Total synthesis of (-)-diospongin A and (+)-cryptofolione via asymmetric aldol reaction
Kumar, Rayala Naveen,Meshram
, p. 1003 - 1007 (2011/03/21)
Stereoselective synthesis of two distinctive pyranone skeletons diospongin A and cryptofolione has been described based on an asymmetric aldol reaction starting from Chan's diene. The synthetic strategy involves the enantioselective Mukaiyama aldol, diast
