1271734-79-2

Basic information

• Product Name: (CH₃)3SiN(Al(C₄H₉)2)C₆H₂(CH₃)3
• CAS NO: 1271734-79-2
• Molecular Weight: 347.595
• Mol File: 1271734-79-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (CH₃)3SiN(Al(C₄H₉)2)C₆H₂(CH₃)3(CAS DataBase Reference)
• NIST Chemistry Reference: (CH₃)3SiN(Al(C₄H₉)2)C₆H₂(CH₃)3(1271734-79-2)
• EPA Substance Registry System: (CH₃)3SiN(Al(C₄H₉)2)C₆H₂(CH₃)3(1271734-79-2)

Safety Data

• Hazardous Substances Data: 1271734-79-2(Hazardous Substances Data)

Upstream product

• 69563-04-8 N-(trimethylsilyl)-2,4,6-trimethylaniline 
• 1191-15-7 diisobutylaluminium hydride 

Relevant articles and documents

Low-coordinate aluminum amides from silylanilines and alkylalanes

The aluminum amides R2AlN(Ar)SiMe3 [R = Et, Ar = Dipp, 1 (Dipp = 2,6-iPr2C6H3-); R = iBu, Ar = Dipp, 2; R = Et, Ar = Mes, 3 (Mes = 2,4,6-Me3C6H 2-); R = iBu, Ar = Mes, 4] were prepared by ethane or hydrogen elimination reaction between Et3Al or iBu2AlH and ArN(H)SiMe3 in refluxing hexane solution. The LiCl salt elimination route resulted in the formation of the monomeric aluminum amide Et 2AlN(Mes)SiPh3 (5) featuring three-coordinate aluminum and nitrogen centers. In addition, the synthesis and characterization of the dinuclear species Ph2Si{N(Mes)AlEt2}2 (6) and the hydride-bridged eight-membered ring compound {MesN(SiMe3)Al(iBu) (μ-H)}2(μ-LiH)(μ-iBu2AlH) (7) are reported. All compounds have been characterized by 1H and 13C{ 1H} NMR spectroscopy, and compounds 5, 6, and 7 have also been characterized by single-crystal X-ray crystallography.