127180-56-7Relevant academic research and scientific papers
REACTION DES FLUOROSILYLOXYRANNES AVEC LES ELECTROPHILES EN PRESENCE D'UNE QUANTITE CATALYTIQUE D'ION FLUORURE
Dubuffet, T.,Sauvetre, R.,Normant, J. F.
, p. 5923 - 5924 (1988)
Formation of nucleophilic species in desilylation of fluorosilyloxyranes by fluoride ion promotes reactions with electrophiles.
Reactivite des fluorosilyloxirannes
Dubuffet, Thierry,Sauvetre, Raymond,Normant, Jean-F.
, p. 677 - 682 (2007/10/02)
Fluorosilyloxiranes have been studied.Ring opening is observed in protic medium (CF3COOH, HF-pyridine) but organometallic reagents associated with Lewis acid do not react. α-Fluorocarbanions are generated from the corresponding organosilicon compounds by the nucleophilic assistance of a catalytic amount of fluoride ion.Fluoroepoxyalcohols and fluoroglycidic acids were obtained.
