127213-05-2

Upstream product

• 108-24-7 acetic anhydride 
• 118068-39-6 methyl 2,3-di-O-benzyl-6-deoxy-6-iodo-α-D-altropyranoside 

Downstream Products

• 127213-06-3 methyl 4-O-acetyl-2,3-di-O-benzyl-α-D-arabinohex-5-enopyranoside 
• 136458-73-6 2L-(2,3,5/4)-2-O-acetyl-3,4-di-O-benzyl-2,3,4,5-tetrahydroxycyclohexanone 
• 136458-77-0 2L-(2,3/4,5)-2-O-acetyl-3,4-di-O-benzyl-2,3,4,5-tetrahydroxycyclohexanone 
• 136458-74-7 2L-(2,3/4)-2-O-acetyl-3,4-di-O-benzyl-2,3,4-trihydroxy-5-cyclohexen-1-one 

Relevant academic research and scientific papers

Synthesis of Optically Active Substituted Cyclohexenones from Carbohydrates by Catalytic Ferrier Rearrangement

Conversion of hex-5-enopyranosides into substituted cyclohexenones (Ferrier rearrangement) was found to proceed efficiently with a catalytic amount of various mercury(II) salts at room temperature in a neutral solvent system.Among the mercury(II) salts tested, mercury(II) trifluoroacetate showed the highest activity.Four optically active cyclohexenones were prepared from hex-5-enopyranosides utilizing this method.