136458-74-7

Upstream product

• 110372-54-8 Acetic acid (1S,2R,3S)-2,3-bis-benzyloxy-4-hydroxy-6-oxo-cyclohexyl ester 
• 17791-36-5 methyl 2,3-di-O-benzyl-α-D-glucopyranoside 
• 127213-05-2 methyl 4-O-acetyl-2,3-di-O-benzyl-6-deoxy-6-iodo-α-D-altropyranoside 
• 118068-39-6 methyl 2,3-di-O-benzyl-6-deoxy-6-iodo-α-D-altropyranoside 
• 127213-06-3 methyl 4-O-acetyl-2,3-di-O-benzyl-α-D-arabinohex-5-enopyranoside 
• 116386-41-5 (3S,4S,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-2-methylene-tetrahydro-pyran-3-ol 
• 87326-88-3 methyl 6-deoxy-6-iodo-2,3-bis-O-(phenylmethyl)-α-D-glucopyranoside 
• 87326-90-7 methyl 4-O-acetyl-2,3-di-O-benzyl-6-deoxy-α-D-xylo-hex-5-enopyranoside 

Downstream Products

• 127243-50-9 1D-(1,3/2,4)-3-O-acetyl-1,2-di-O-benzyl-5-cyclohexene-1,2,3,4-tetrol 
• 1313193-72-4 C₂₁H₂₂O₅ 
• 1313586-79-6 (+)-4-epi-gabosine E 
• 1376712-09-2 (1S,5S,6R)-5,6-bis(benzyloxy)-3-((S)-(4-cyanophenyl)(hydroxy)methyl)-2-oxocyclohex-3-enyl acetate 
• 1376712-14-9 (1S,5S,6R)-5,6-bis(benzyloxy)-3-((R)-(2,3-dichlorophenyl)(hydroxy)methyl)-2-oxocyclohex-3-enyl acetate 
• 1376712-11-6 (1S,5S,6R)-5,6-bis(benzyloxy)-3-((R)-(2-fluorophenyl)(hydroxy)methyl)-2-oxocyclohex-3-enyl acetate 
• 1376712-18-3 (4S,6S,7R,8R,8aS)-6,7-bis(benzyloxy)-4-(4-cyanophenyl)-2,2-dimethyl-6,7,8,8a-tetrahydro-4H-benzo[d][1,3]dioxin-8-yl acetate 
• 1376712-08-1 (1S,5S,6R)-5,6-bis(benzyloxy)-3-((S)-hydroxy(4-nitrophenyl)methyl)-2-oxocyclohex-3-enyl acetate 
• 1376712-13-8 (1S,5S,6R)-5,6-bis(benzyloxy)-3-((S)-(4-chlorophenyl)(hydroxy)methyl)-2-oxocyclohex-3-enyl acetate 
• 1376712-12-7 (1S,5S,6R)-5,6-bis(benzyloxy)-3-((R)-(2,4-difluorophenyl)(hydroxy)methyl)-2-oxocyclohex-3-enyl acetate 
• 1313193-70-2 C₂₃H₂₄O₆ 
• 122777-39-3 1D-(1,2,3/4)-3,4-di-O-benzyl-2-<(tert-butoxycarbonyl)amino>-1-O-tetrahydropyranyl-5-cyclohexene-1,3,4-triol 
• 127213-13-2 1D-(1,3/2,4)-1,2-di-O-benzyl-3-O-(methanesulfonyl)-4-O-tetrahydropyranyl-5-cyclohexene-1,2,3,4-tetrol 
• 122777-38-2 1D-(1,2,3/4)-2-azido-3,4-di-O-benzyl-1-O-tetrahydropyranyl-5-cyclohexene-1,3,4-triol 

Relevant academic research and scientific papers

Syntheses of (-)-gabosine A, (+)-4-epi-gabosine A, (-)-gabosine E, and (+)-4-epi-gabosine e

(+)-4-epi-Gabosine A 1 and (-)-gabosine A 2 have been synthesized starting from methyl α,d-glucopyranoside and methyl α,d-mannopyranoside, respectively, by utilizing Pd(0) catalyzed Stille coupling as the key step. On the other hand, syntheses of (+)-4-ep

Synthesis of Optically Active Substituted Cyclohexenones from Carbohydrates by Catalytic Ferrier Rearrangement

Conversion of hex-5-enopyranosides into substituted cyclohexenones (Ferrier rearrangement) was found to proceed efficiently with a catalytic amount of various mercury(II) salts at room temperature in a neutral solvent system.Among the mercury(II) salts tested, mercury(II) trifluoroacetate showed the highest activity.Four optically active cyclohexenones were prepared from hex-5-enopyranosides utilizing this method.

Total Synthesis of Antibiotic Hygromycin A

The first total synthesis of the antibiotic (-)-hygromycin A (1) has been achieved by a coupling reaction of the sugar moiety (2) and the cyclitol moiety (3).Both components were synthesized in homochiral forms starting from D-glucose.This synthesis fully

Total Synthesis of Hygromycin A

The first complete synthesis of antibiotic hygromycin A is reported; coupling of the protected sugar moiety (2) and the aminocyclitol (3) derived from D-glucose as the optically active form, followed by deprotection, gives the product (1) which was identi