127253-92-3Relevant academic research and scientific papers
Asymmetric Synthesis XVII : Facile Generation of a Chiral Azomethine Ylide via the CN(R,S) Method
Rouden, Jacques,Royer, Jacques,Husson, Henri-Philippe
, p. 5133 - 5136 (2007/10/02)
(-)-N-cyanomethyl-4-phenyl-1,3-oxazolidine, prepared in one step from R-(-)-phenylglycinol, gives a chiral azomethine ylide on treatment with TMSOTf and (iPr)2NEt.This ylide undergoes 1,3-dipolar cycloaddition reactions with activated olefins under very m
