127296-19-9Relevant academic research and scientific papers
ON CATALYZED AND UNCATALYZED HYDROBORATIONS OF CHIRAL ALLYLIC ALCOHOLS AND AMINES
Burgess, Kevin,Ohlmeyer, Michael J.
, p. 5861 - 5864 (1989)
A model for predicting the sense of diastereoselection in catalyzed hydroborations of allylic alcohol and allylic amine derivatives is discussed.
Substrate-Controlled Diastereoselectivities in Catalyzed and Uncatalyzed Hydroborations of Acyclic Allylic Alcohol Derivatives: Secondary Orbital Effects Involving d?-p? Interactions
Burgess, Kevin,Cassidy, Juanita,Ohlmeyer, Michael J.
, p. 1020 - 1027 (2007/10/02)
Rhodium-mediated hydroborations of allylic alcohol derivatives 1-9 followed by oxidation give predominantly syn-2-methyl 1,3-diols whereas conventional hydroborations of the same substrates afford mostly anti products.It is proposed that mixing of ?*
