132317-36-3Relevant academic research and scientific papers
Substrate-Controlled Diastereoselectivities in Catalyzed and Uncatalyzed Hydroborations of Acyclic Allylic Alcohol Derivatives: Secondary Orbital Effects Involving d?-p? Interactions
Burgess, Kevin,Cassidy, Juanita,Ohlmeyer, Michael J.
, p. 1020 - 1027 (1991)
Rhodium-mediated hydroborations of allylic alcohol derivatives 1-9 followed by oxidation give predominantly syn-2-methyl 1,3-diols whereas conventional hydroborations of the same substrates afford mostly anti products.It is proposed that mixing of ?*
