1273386-85-8Relevant articles and documents
Addition of TMS-substituted oxiranyl anions to acylsilanes. A highly stereoselective approach to tetrasubstituted (Z)-β-hydroxy-α-TMS silyl enol ethers
Song, Zhenlei,Kui, Leizhou,Sun, Xianwei,Li, Linjie
supporting information; experimental part, p. 1440 - 1443 (2011/05/03)
A highly stereoselective approach to novel tetrasubstituted (Z)-β-hydroxy-α-TMS silyl enol ethers is described. The reaction proceeds via a sequential addition/[1,2]-Brook rearrangement/epoxide-opening process of TMS-substituted oxiranyl anions with acyls