1274751-19-7Relevant articles and documents
Palladium(II)-catalyzed c-h bond arylation of electron-deficient arenes at room temperature
Tredwell, Matthew J.,Gulias, Moises,Gaunt Bremeyer, Nadine,Johansson, Carin C. C.,Collins, Beatrice S. L.,Gaunt, Matthew J.
supporting information; experimental part, p. 1076 - 1079 (2011/04/16)
Mild and tolerant: A novel PdII-catalyzed C-H bond arylation with aryl-BF3K salts transforms various electron-deficient arenes under mild reaction conditions. Benzaldehydes are functionalized in the ortho position using a temporary imine directing group that controls the cyclopalladation. A broad range of benzaldimines are compatible with this process (see scheme).