1274764-51-0Relevant articles and documents
Rhodium(III)-catalyzed alkenyl C-H bond functionalization: Convergent synthesis of furans and pyrroles
Lian, Yajing,Huber, Tatjana,Hesp, Kevin D.,Bergman, Robert G.,Ellman, Jonathan A.
supporting information, p. 629 - 633 (2013/02/23)
Ring in the new: A new annulation for the efficient synthesis of substituted furans and pyrroles is reported. The RhIII-catalyzed reaction of O-methyl α,β-unsaturated oximes with aldehydes and N-tosyl imines affords secondary alcohol and amine intermediates, respectively. Cyclization and aromatization occurs under the reaction conditions to provide access to biologically relevant furans and pyrroles in good yields. Cp=C5Me5, DCE=1,2-dichloroethane, THF=tetrahydrofuran. Copyright
