127541-70-2Relevant academic research and scientific papers
π-facial selectivity in catalytic osmylation reactions of chiral C1-oxygenated allylic silanes
Panek, James S.,Cirillo, Pier F.
, p. 4873 - 4878 (2007/10/02)
Oxygen-substituted allylic and crotyl silanes undergo vicinal hydroxylations with unprecedented levels of diastereofacial selectivities in the presence of catalytic amounts of osmium tetroxide to predominantly form 1,2-anti-1,2,3-triol units. The magnitud
