1275577-95-1

Basic information

• Product Name: [Ru(η4-butadiene)(η4-1,5-cyclooctadiene)(PPh3)]
• CAS NO: 1275577-95-1
• Molecular Weight: 525.636
• Mol File: 1275577-95-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ru(η4-butadiene)(η4-1,5-cyclooctadiene)(PPh3)](CAS DataBase Reference)
• NIST Chemistry Reference: [Ru(η4-butadiene)(η4-1,5-cyclooctadiene)(PPh3)](1275577-95-1)
• EPA Substance Registry System: [Ru(η4-butadiene)(η4-1,5-cyclooctadiene)(PPh3)](1275577-95-1)

Safety Data

• Hazardous Substances Data: 1275577-95-1(Hazardous Substances Data)

Upstream product

• 106-99-0 buta-1,3-diene 

Relevant articles and documents

Stoichiometric and catalytic cross dimerization between butadiene and methyl acrylate promoted by a Ruthenium(0) complex

Treatment of Ru(η4-butadiene)(η4-1,5-COD) (NCMe) (1a) with methyl acrylate in benzene for 3 h at 6 °C produces Ru{cisoid-η4-(2E,4E)-(methyl hepta-2,4-dienoate)} (η4-1,5-COD)(NCMe) (2a) in 97% yield. Complex 1a (2 mol %) catalyzes the chemoselective cross dimerization between butadiene and methyl acrylate in benzene to give a mixture of the regioisomers of methyl heptadienoate in 43% yield by the oxidative coupling reaction.