127559-95-9Relevant academic research and scientific papers
Activation of Carbon Dioxide: Nickel-Catalyzed Electrochemical Carboxylation if Diynes
Derien, Sylvie,Clinet, Jean-Claude,Dunach, Elisabet,Perichon, Jacques
, p. 2578 - 2588 (2007/10/02)
The simualtaneous activation of carbon dioxide and diynes by electrogenerated LNi(0) complexes (L=bpy, pentamethyldiethylenetriamine: PMDTA) enables the selective incorporation of one molecule of CO2 into the unsaturated systems and the preparative-scale
Electrogenerated nickel(0) catalyzed carbon dioxide incorporation into α,ω-diynes
Derien, S.,Dunach, E.,Perichon, J.
, p. C43 - C46 (2007/10/02)
Electrogenerated low-valent nickel complexes are active catalysts for carbon dioxide incorporation into α,ω-diynes.A strong influence of the nature of the ligand on the selectivity of this carboxylation has been observed.
