127583-01-1Relevant articles and documents
Stereoselective Reduction of α-Cyclopropyl Ketones and α-Cyclopropyl Aldols. Stereo-directing Effect by α-Trimethylsilyl Group
Shimazaki, Masato,Hara, Hisaaki,Suzuki, Keisuke
, p. 5447 - 5450 (1989)
Stereoselective reduction of α-chiral α-cyclopropyl ketones and α-cyclopropyl aldols is described.Introduction of trimethylsilyl (TMS) group to the α-position of cyclopropyls leads to virtually complete stereoselection to give the stereo-defined β-cyclopr